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Title：This mini-review summarized the recent progress in the conceptual design of polymer–ceramic hybrid antifouling coatings, and how stereoscopic polysiloxanes affect the mechanical and antifouling properties of the final coatings.

Abstract: Simultaneous realization of superior mechanical and antifouling properties is critical for a coating. The use of stereoscopic polysiloxanes in place of linear polysiloxanes to fabricate antifouling coatings can combine properties of organic and inorganic materials, i.e., they can exhibit both high hardness and wear resistance from inorganic components as well as the flexibility and tunability from organic components. This strategy is used to prepare hard yet flexible antifouling coatings or polymer-ceramic hybrid antifouling coatings. In this mini-review, we report the recent advances in this field. Particularly, the effects of stereoscopic polysiloxane structures on their mechanical and antifouling properties are discussed in detail.